电催化剂
材料科学
双功能
镍
电解
析氧
分解水
电解质
无机化学
阳极
化学工程
催化作用
电解水
电极
阴极保护
电化学
冶金
化学
生物化学
光催化
工程类
物理化学
作者
Jianfang Zhang,Yang Li,Tianyu Zhu,Yan Wang,Jiewu Cui,Jingjie Wu,Hui Xu,Xiaoyan Shu,Yongqiang Qin,Hongmei Zheng,Pulickel M. Ajayan,Yong Zhang,Yucheng Wu
标识
DOI:10.1021/acsami.8b09361
摘要
High-performance noble metal-free electrocatalysts are extremely desired for overall water splitting, but there are huge challenges. Herein, we report a novel one-step electrochemical anodic oxidation and cathodic deposition strategy to in situ fabricate three-dimensional coral-like Ni3S2 on Ni foam (NF) for electrocatalytic overall water splitting. In a typical two-electrode cell, NF acts as both cathodic and anodic electrodes with thiourea aqueous solution as the electrolyte. The nickel ions from the anodic oxidation of NF are directly used as nickel sources to form 3D coral-like Ni3S2/NF by the cathodic deposition method simultaneously. The optimal 3D Ni3S2/NF-4 electrode shows high electrocatalytic activity for hydrogen evolution reaction and oxygen evolution reaction with low overpotentials of 89 and 242 mV, respectively, to afford 10 mA cm-2. When the as-obtained Ni3S2/NF-4 is used as a bifunctional electrocatalyst in an electrolyzer, a low applied voltage of 1.577 V is needed to reach 10 mA cm-2, with extremely long durability. This work focuses on the rational design of unique structures as efficient non-noble metal-based electrocatalysts, which hold great potential for practical applications in electrocatalytic water splitting.
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