The Z-scheme NH2-UiO-66/PTCDA composite for enhanced photocatalytic Cr(VI) reduction under low-power LED visible light

Series Z-scheme NH2-UiO-66/PTCDA (NU100PX) composites constructed from NH2-UiO-66 and PTCDA (3,4,9,10-perylenetetracarboxylic dianhydride) were obtained by simple ball-milling method. The photocatalytic Cr(VI) reduction activities of the NU100PX composites were conducted upon the irradiation of low power LED visible light. The results revealed that the introduction of a small amount of PTCDA on the surface of NH2-UiO-66 could broaden the light absorption range and boost the separation of photo-induced charge carriers to promote the photocatalysis efficiency. The influence factors toward photocatalytic Cr(VI) cleanup performances of NU100P10 like pH, initial Cr(VI) concentrations, the impacts of small organic acids as hole capture agents along with various co-existing foreign matters were clarified. After 5 runs’ adsorption-photoreduction towards Cr(VI), the NU100P10 still exhibited superior reduction activity and reusability. The Z-scheme mechanism of photocatalytic Cr(VI) removal over NU100P10 was put forward and certificated by electrochemical experiment, ESR (electron spin resonance) test, XPS determination, photo-deposition and DFT (density functional theory) calculation.