化学
试剂
卤化物
稀土
烷基
组合化学
有机化学
纳米技术
矿物学
材料科学
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2022-01-31
卷期号:122 (6): 6040-6116
被引量:30
标识
DOI:10.1021/acs.chemrev.1c00842
摘要
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl and organoaluminate complexes. This review collates the most important starting materials used in RE synthetic chemistry, including essential information on their preparations and uses in modern synthetic methodologies. The review is divided by starting material category and supporting ligands (i.e., metals as synthetic precursors, halides, borohydrides, nitrogen donors, oxygen donors, triflates, and organometallic reagents), and in each section relevant synthetic methodologies and applications are discussed.
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