接受者
材料科学
有机太阳能电池
三元运算
光伏系统
丙二腈
能量转换效率
化学工程
有机化学
化学
光电子学
催化作用
聚合物
复合材料
工程类
程序设计语言
生态学
物理
生物
计算机科学
凝聚态物理
作者
Weixuan Liang,Peng Liu,Yiheng Zhang,Weiya Zhu,Tao Xinyang,Zhengjie He,Yuan Li
标识
DOI:10.26434/chemrxiv-2021-plssb-v2
摘要
Non-fullerene acceptors exhibit great potential to improve photovoltaic performances of organic solar cells. However, it is important to further enhance chemical stability and device durability for future commercialization, especially for Y6-series small molecule acceptors with 2-(3-oxo-2,3-dihydroinden-1-ylidene)malononitrile (IC) type as ending group. In this work, an IC-free photovoltaic material YF-CN consisting of 2-fluoren-9-ylidenepropanedinitrile terminal was designed and synthesized by stille coupling. YF-CN exhibited closed-shell chemical structure with enhanced photostability and improved morphological compatibility with the binary PCE10:Y6 blend. The moderate energy level makes YF-CN could serve as a multifunctional material, such as donor, acceptor and the third component. When adding YF-CN as second donor into PCE10:Y6 system, an improved power conversion efficiency of 12.03% was achieved for as-cast device. Importantly, the ternary PCE10:YF-CN:Y6-devices showed enhanced storage durability maintaining 91% of initial PCE after the 360 hours. This work provides new perspective to understand the open-shell character of donor and closed-shell structure of acceptors, respectively, as well as promising design concept of stable IC-free acceptors for organic solar cells.
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