Lunar compositional asymmetry explained by mantle overturn following the South Pole–Aitken impact

The spatial distribution of mare basalts, titanium and KREEP (potassium, rare earth elements and phosphorus) on the Moon is asymmetrical between the nearside and farside. These asymmetries cannot be readily explained by solidification of a global magma ocean and subsequent mantle overturn, which should result in a layered and spherically symmetric lunar interior. Alternative scenarios have been proposed to explain the observed compositional asymmetry, but its origin remains enigmatic. Here, we present hydro- and mantle convection numerical simulations of the giant impact event that formed the South Pole–Aitken basin—the largest impact basin on the Moon—and the subsequent impact-induced convection with the assistance of gravitational instability. We find that the impact induces thermochemical instabilities that drive the dense KREEP-rich ilmenite-bearing cumulate to migrate towards the nearside following lunar magma ocean solidification. This results in the formation of a chemical reservoir under the nearside crust that could explain the observed geochemical asymmetries. We suggest that enrichments of ilmenite and KREEP in the nearside hemisphere following the South Pole–Aitken impact event provide a viable explanation for the wide composition range of mare basalts observed on the lunar surface.