Unveiling the urease like intrinsic catalytic activities of two dinuclear nickel complexes towards the in situ syntheses of aminocyanopyridines

O) (2) [HL1 = 2,4-dimethyl-6-{[(2'-dimethyl aminoethyl)methylamino]methyl}-phenol and HL2 = 2,4-dichloro-6-{[(2'-dimethyl aminoethyl)methylamino]methyl}-phenol] have been synthesized and characterized in this report. Both the complexes have shown the urease kind of activity with the liberation of ammonia from urea in aqueous solution. The plausible mechanistic pathway and kinetics of the reactions have been studied. Besides, the liberated ammonia has been utilized in the one-pot synthesis of biologically active products like 2-amino-3-cyanopyridines and their derivatives in aqueous medium with excellent yields.