Landscaping Covalent Organic Framework Nanomorphologies

The practical utilization of covalent organic frameworks (COFs) with manipulation at the atomic and molecular scale often demands their assembly on the nano-, meso-, and macroscale with precise control. Consequently, synthetic approaches that establish the ability to control the nucleation and growth of COF crystallites and their self-assembly to desired COF nanomorphologies have drawn substantial attention from researchers. On the basis of the dimensionality of the COF morphologies, we can categorize them into zero- (0-D), one- (1-D), two- (2-D), and three-dimensional (3-D) nanomorphologies. In this perspective, we summarize the reported synthetic strategies that enable precise control of the COF nanomorphologies' size, shape, and dimensionality and reveal the impact of the dimensionalities in their physicochemical properties and applications. The aim is to establish a synergistic optimization of the morphological dimensionality while keeping the micro- or mesoporosity, crystallinity, and chemical functionalities of the COFs in perspective. A detailed knowledge along the way should help us to enrich the performance of COFs in a variety of applications like catalysis, separation, sensing, drug delivery, energy storage, etc. We have discussed the interlinking between the COF nanomorphologies via the transmutation of the dimensionalities. Such dimensionality transmutation could lead to variation in their properties during the transition. Finally, the concept of constructing COF superstructures through the combination of two or more COF nanomorphologies has been explored, and it could bring up opportunities for developing next-generation innovative materials for multidisciplinary applications.