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A continuous electrospinning technique is designed to interweave oxide solid electrolytes into electrode/electrolyte integrated ultra‐thin films, which have a continuous three‐dimensional ion transport network, high ion conductivity, and particularly significant lithium metal stability. The assembled symmetrical battery exhibits excellent cycling stability, due to the effect of high‐performance polymer ceramic nanoparticle reinforced fiber ultra‐thin film and the synergistic effect of integrated spinning process on cathode and lithium metal. The solid electrolyte film prepared by positive electrode interface continuous spinning technology forms a stable, ultra‐thin, and compact interface, exhibiting excellent electrochemical performance and high energy density, paving the way for the application of high‐performance composite solid‐state batteries. image