化学
光催化
催化作用
光催化
过渡金属
纳米技术
电子转移
光化学
基质(水族馆)
能量转移
组合化学
化学物理
有机化学
海洋学
地质学
材料科学
作者
Amy Y. Chan,Ian B. Perry,Noah B. Bissonnette,Benito F. Buksh,Grant A. Edwards,Lucas I. Frye,Olivia L. Garry,Marissa N. Lavagnino,Beryl X. Li,Yufan Liang,Edna Mao,Agustin Millet,James V. Oakley,Nicholas L. Reed,Holt A. Sakai,Ciaran P. Seath,David W. C. MacMillan
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2021-11-18
卷期号:122 (2): 1485-1542
被引量:661
标识
DOI:10.1021/acs.chemrev.1c00383
摘要
The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. This Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.
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