Influences of assembly pressure and flow channel size on performances of proton exchange membrane fuel cells based on a multi-model

质子交换膜燃料电池 流量(数学) 燃料电池 频道(广播) 化学 材料科学 机械 化学工程 计算机科学 物理 工程类 电信 生物化学
作者
Lei Shi,Sichuan Xu,Jinling Liu
出处
期刊:International Journal of Hydrogen Energy [Elsevier BV]
卷期号:47 (12): 7902-7914 被引量:25
标识
DOI:10.1016/j.ijhydene.2021.12.097
摘要

In this work, assembly pressure and flow channel size on proton exchange membrane fuel cell performance are optimized by means of a multi-model. Based on stress-strain data of the SGL-22BB GDL obtained from its initial compression experiments, Young's modulus with different ranges of assembly pressure fits well through modeling. A mechanical model is established to analyze influences of assembly pressure on various gas diffusion layer parameters. Moreover, a CFD calculation model with different assembly pressures, channel width, and channel depth are established to calculate PEMFC performances. Furthermore, a BP neural network model is utilized to explore optimal combination of assembly pressure, channel width and channel depth. Finally, the CFD model is used to validate effect of size optimization on PEMFC performance. Results indicate that gap change of GDL below bipolar ribs is more remarkable than that below channels under action of the assembly pressure, making liquid water easily transported under high porosity, which is conducive to liquid water to the channels, reduces the accumulation of liquid water under the ribs, and enhances water removal in the PEMFC. Affected by the assembly force, change of GDL porosity affects its diffusion rate, permeability and other parameters, which is not conducive to mass transfer in GDL. Optimizing the depth and different dimensions through width of the flow field can effectively compensate for this effect. Therefore, the PEMFC performance can be enhanced through the comprehensive optimization of the assembly force, flow channel width and flow channel depth. The optimal parameter is obtained when assembly pressure, channel width and channel depth are set as 0.6 MPa, 0.8 mm, and 0.8 mm, respectively. The parameter optimization enhances the mass transfer, impedance, and electrochemical characteristics of PEMFC. Besides, it effectively enhances the quality transfer efficiency inside GDL, prevents flooding, and reduces concentration loss and ohmic loss. • Influences of assembly pressure and flow channel size on PEMFC performances are investigated. • Initial compression parameters of SGL-22BB GDL makes a mechanical model for the GDL close to reality. • A multi-parameter optimization method based on BP neural network is proposed. • Mass transfer, impedance and electrochemical characteristics of PEMFC are improved through optimization of the parameters.

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